[For the New Readers: This is a continuation of the discussion started in Episode 1.]
What is the
Wave-Particle Duality?
WARNING: PUT
YOUR IMAGINATION CAPS ON! WE ARE ENTERING DANGEROUS TERRITORY.
You see this is the main source of confusion and
misunderstanding in all of Quantum Mechanics. If we understand this
well, we're half way through.
In
the beginning of the last century, physicists came to notice that
under certain very delicate situations, the electromagnetic waves –
I said “waves” mark it! – seemed to behave like particles.
Particles? But how can that possibly be? Waves and particles are
totally opposite kind of things (you should be able to appreciate
this now). How can delocalized waves which can pass through one
another and interfere to add up or cancel each other, behave like
localized particles which hit each other and bounce off? Well, no one
knows! Not even today. Then how does it make sense at all? It doesn't
– thinking classically.
Soon
it was found that electrons behave in the same way, that is they are
screwy exactly the same way as photons are. They behave like
particles or waves or both or neither depending upon the experiment.
So
what are these electrons? Particles? Waves? If waves, then waves of
what? No one knows. Now we have given up on thinking about these
questions on how crazy nature behaves. We think differently now. We
think quantum mechanically. That is to say, we don't know and we
believe, even nature doesn't know what is going on down at those tiny
scales. But there is still a certain order to things, and that order
is encapsulated in the theory of quantum mechanics.
You
see the whole of quantum mechanics is based on three fundamental
postulates: (1) The Superposition Principle,
(2) The Measurement Principle
and (3) Unitary Evolution.
Objects such as electrons or photons or any thing for that matter (I call them objects because I don't know whether to call them particles or waves or both or neither) have a certain wave-function associated with them that describes their state. I do not know what that wave is. I cannot physically measure it in any way possible. Trust me on this, I simply cannot. In an em-wave, I know the fields oscillate. In sound waves, pressure through air oscillates. In water waves, the water surface level oscillates. In this case, I do not know what shit oscillates. But I know this: the oscillations can have complex amplitudes (seriously?) and the absolute value squared of the amplitude is a measure of the probability distribution function describing the probability of existence of an object (as a particle) in a certain definite position for example. Now that is something I can measure! If there are several alternatives an object can take, there is an amplitude associated with each of these alternatives, and the state of the object is a vector sum of all these amplitudes. This is known as the Superposition Principle. It means nature does not know anything about which of the alternatives it should take (eg. which position it should occupy). It is in a superposition of all the alternatives. I don't know what that means though.
Difficult to understand? Well take the example of the double-slit
experiment with electrons shot one at a time. If we think that the
electron went through either one "OR" the other slit but
not through both, we would run into very fundamental logical
inconsistencies
if at the same time we observed an interference pattern at the other
end of the setup; but we do observe an interference pattern and
therefore we must shun our intuition, our classical notion about a
particle taking only one "OR" the other of all the
available possibilities. Does that mean the particle goes through
both the slits (splitting into half, going through both slits and
interfering with itself), that particles in general "exist"
in a fuzzy state taking up all the available possibilities at the
same time? Well, we don't know. And we leave such questions for
jobless philosophers to answer, because if we try to answer this
question experimentally (like all physicists do), we find out that
the particle goes through either slit1 or slit2, but not both. But
having found that out, we do not run into any logical inconsistencies
because nature leaves us without any interference and we're
dumbstruck at her subtlety you see.
Two important fundamental principles of quantum mechanics are deduced
from this experiment: 1) THE SUPERPOSITION PRINCIPLE which, as we
have discussed earlier, states that there are amplitudes associated
with any observation (the intensity or square of which is a measure
of the probability of that observation to occur) and the resultant
amplitude which describes the state of the system is a superposition
of the amplitudes associated with all the possibilities that may
exist for the system. 2) THE MEASUREMENT PRINCIPLE which states that
a measurement of the state of the system reveals only partial
information about it, reducing the resultant amplitude to just ONE of
the total possibilities. This is also known as the collapse of the
wave-function. It is only after a measurement is made that nature
decides upon which of the alternatives she should take.
Take
a break now! It's a lot to digest. Ruminate on what you have just
read. Probably read the paragraphs again and then proceed. I would
advise you read them twice and think about them thrice.
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Let
us investigate a little bit more about what these wave-functions are.
Read about the meaning of unitary evolution yourself. It just
stresses on the fact that a particle, at any given instant of time,
almost surely takes up at least one of the infinite plethora of
possibilities. For example, I would expect the probability that an
electron is somewhere there in the limitless vastness of space, to be
equal to unity. A wave-function that ensures that, is called a
normalized wave-function. The time evolution of wave-functions must
preserve this normalization condition. The principle of unitary
evolution is thus also known by the name 'principle of conservation
of probability.' I will not talk about it now. You read it yourself.
Cool? It's easy shit, but a very useful concept.
Think
about this question. Where is the wave? Where does it float? Space
obviously – the space around us, isn't it? Well, I would not shoot
a “yes” right away at this. There is a certain amount of
mathematical subtlety that you need to understand here. What is this
space if I may ask? It is the set of all positions, is it not? Yes,
of course! But I call that space by a special name: the position
configuration space, because I consider the set of positions which
would specify a configuration of the object I might want to study, in
terms of the object's position or positions of the constituents of
the object. Mostly when I say space I mean the position configuration
space. But I can have other configuration spaces as well, for example
the momentum configuration space which is the set of all momenta that
an object can take. Here I will not have the x, y and
z-axes, but perhaps px, py
and pz-axes. Suppose I know of a
wave-function ø(x,t)
in the position space
and I ask, how does it look in the momentum space? What is the form
of ø(p,t)?
How do I do that? Do you know it? I will give you a hint! You have
already come across this transformation several times, perhaps
unknowingly but you have for sure. It obviously has something to do
with position and momentum. Stop! Make a guess first before reading
any further.
Well,
don't be surprised when I tell you it's a Fourier transform. It comes
from the famous de Broglie's relation which postulates that if the
wave-function associated with a single object, ø(x,t)
be
an infinite plane wave of fixed wave number k0
(remember
this implies that the object is completely delocalized in space: it
is in a superposition of all the infinite number of positions,
equally weighted – close your eyes and imagine, my friend!), then
the object has a fixed momentum given by p0=ħk0.
Thus
in the momentum space, the wave-function looks like a sharp spike at
p=p0
(it
is a Dirac-delta function to be precise). You should be knowing from
your study of mathematics that the Fourier transform of a plane wave
is a Dirac-delta. In general, the transformation from the position
configuration space to momentum configuration space and vice versa is
accomplished by Fourier transforms. Period! There are reasons why it
is a Fourier transform. It has to do with the superposition
principle. It is a very beautiful picture actually. But I'll keep
that tale for some other day. Right now, just get this straight. An
object completely delocalized in the position space (thus meaning a
plane wave associated with it) has a fixed definite momentum and
conversely, an object completely delocalized in the momentum
configuration space has a fixed definite position. An object
partially delocalized in one of the configuration spaces would also
be partially delocalized in the other configuration space.
But
why do we need to look at it from another perspective? Is not
position configuration space enough? Why do we need all these other
configuration spaces?
Well,
imagine this scenario. Say you have a nice wave-function ø(x,t)
in the position space, in case of an electron for example. You
would expect the probability distribution function ℙ(x,t)
to be equal to the intensity of that wave, that is to say
ℙ(x,t)=|ø(x,t)|2.
Now see that means, the object is not fixed at any position x
but has a certain probability of being at any position x
ranging from minus infinity to plus infinity. However, since you know
the probability density ℙ(x,t),
you can calculate the mean position xmean
very easily from the formula you should be knowing from your
study of elementary statistics and probability: just integrate x.ℙ(x,t) from minus infinity to plus infinity. xmean
in general would be a function just of time. But keep in mind that
the electron is not just there in the position x=xmean,
it is in fact everywhere until you make a measurement to find out
where it is. You cannot really predict deterministically the outcome
of such a measurement. The result would be random. However, if you
make simultaneous measurements on a large number of identical
systems, you would mostly find the electron to be near x=xmean
. Now suppose we want to know the momentum of the electron.
What do we do? Since the mean changes with time, is the momentum
proportional to the time derivative of xmean?
But we can't be sure about this, because xmean
is just the mean position. We have no conception about the idea of a
classical position here. We are dealing with average values for God's
sake. So how do we go about it?
There,
you see! Because we know how to transform to the momentum
configuration space, we can go about finding how the probability
distribution function appears like in this space. Once we have the
distribution over momentum space ℙ(p,t)=|ø(p,t)|2,
we can very easily calculate the average momentum pmean
using the same formula that we know from elementary statistics. Well
it turns out that the average momentum is proportional to the time
derivative of the average position (the proportionality constant
being the electron's mass). That's an unexpected surprise but a
pleasant surprise indeed. (It also turns out that the time derivative
of the average momentum is equal to the average force – voila!
Newton's law hidden in averages, another pleasant surprise!). Do keep
in mind that these are just averages we are dealing with. In general,
there will be a non-zero standard deviation from the mean.
So now you see the usefulness of different configuration spaces. If you
want to find the mean of an observable quantity of your interest,
just transform to that specific configuration space and then it is
all very easy. For example, you want the average energy, go to the
energy configuration space and compute the mean from the formula you
know.
Take
a deep breath now. Let me summarize by pointing out what we have
learnt about wave-functions a.k.a. matter
waves in this long discussion.
Wave-functions
do not mean point-like particles traveling in a sinusoidal path.
That is a very wrong picture (and means you haven't understood the
concept of waves well)! Matter-waves are mathematical waves of some
uncanny shit which we cannot possibly imagine in a thousand years.
However their intensities have a precise physical significance. They
are probability distribution functions. E.g. a plane wave ø(x,t)=Aexp[i(kx–wt)] may be associated with an object but would never be physically
observable. However, |ø(x,t)|2=A2
is
a physically measurable quantity – the probability distribution!
Electrons, photons and all
objects in this universe do not behave like particles, neither do
they behave like waves. They behave like nothing we have ever had
any direct experience with. We call them matter-waves. But we do not
know what they are, how they look or what they do, but only that
they exist because we have seen what happens to the world when they
interfere. They do have observable consequences by which they make
their presence felt – and that is how we study them! However,
whenever we make any measurement, the wave-function collapses!
Wave-functions need not be
plane waves always. In fact, to tell you the truth, they never
really are. Plane waves are non-physical wave-functions because they
are non-normalizable (check it!). However, you should know from your
knowledge of Fourier analysis that if you stack together a lot of
different plane waves, you can make up any nice function you want –
that includes good normalizable waves that represent physical
systems in our world. E.g. The wave described by ø(x,t)=Aexp[–b|x|–iwt] (try to imagine how that function looks like) is a nice
normalizable function but is not a plane wave.
UPCOMING: What's the fuss about the Uncertainty Rule?
Check it out in Episode 3.
For
mathematical and technical details, contact me.